Radionuclide Fact Sheet
TRITIUM (HYDROGEN - 3)
Symbol: 3H
States/Forms: Soluble, except gaseous
Physical Characteristics
- Radioactive Half Life (T½): 12.3 years
- Decay Type: Beta- (ß-)
- Maximum Energy Emission: 0.0186 MeV
- Maximum Range in Air: 0.6 cm
- Maximum Range in Water/Tissue: 0.0006 cm
Hazard Category
- A Level (High Hazard): >10.0 Ci
- B Level (Moderate Hazard): >25 mCi per item to 10.0 Ci possession
- C Level (Low Hazard): 1-25 mCi per item to 100mCi possession
Radiological Characteristics
- 0% of beta particle energy transmitted through dead layer of skin.
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Critical organ: Body water or tissue.
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Routes of intake: Ingestion, inhalation, puncture, wound, skin contamination (absorption).
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Internal exposure and contamination: Primary radiological concerns with 3H.
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External exposure: External exposure from weak 3H beta particles is not a major radiological concern
Dosimetry
- Film badges and dosimeter rings are not appropriate for monitoring 3H exposure.
Bioassay Requirements
- Routine urinalysis is required after handling 100 microcuries (μCi) or greater of 3H. Spot checks may be necessary following spills or incidents of contamination.
External Radiation Hazards and Shielding
- There is minimal external hazard with 3H, i.e. the vial containing the 3H provides sufficient shielding from the beta particles. If the skin is contaminated with 3H, the betas will not be able to penetrate through the dead layer of skin. However, if 3H is absorbed into the body via ingestion or cuts in the skin, it will cause a radiation dose.
Hazards if Internally Deposited
ALI (Annual Limit of Intake)
- 80 mCi – by ingestion or inhalation
DAC (Derived Air Concentration)
- 2.0 x 10-5 μCi/mL
Survey Instrumentation
- Tritium cannot be detected using a Geiger-Muller or NaI survey meter.
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Smear surveys, using liquid scintillation counters, are required to detect 3H contamination.
Problems and Precautions
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Lab coats and protective gloves should always be worn when working with 3H to keep skin free from contamination, and gloves should be changed often.
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All waste in a 3H work area is considered to be contaminated. Work areas should be kept free of unnecessary items.
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Wastes should be segregated to those with 3H and 14C only.