LIMESTONE CONTACTORS

 LIST OF CONTENTS

  Introduction

  Process Description

  Typical Contactor

  Design Criteria

  Photos, Plans & Specs

  Treatment Performance

  Operational Skills

  Automation Potential

  Advantages

  Limitations & Concerns

  Pilot Plant Objectives

  Costs 

  References

  Contacts & Facilities

 

PROCESS DESCRIPTION - CONTINUED

1.2. DIC content:
DIC is the sum of all carbonate containing species. It is represented by CT,CO3 as shown in 9. If the concentrations of complexes are assumed to be negligibly small, the DIC concentration is the sum of H2CO3*, HCO3- and CO32- concentrations. DIC content governs the equilibrium of the carbonate system and the level of CaCO3 saturation. It affects the dissolution rate because it affects the extent of CaCO3 undersaturation.

1.3. Temperature:
Limestone dissolution rate increases as the temperature of water increases (Cox, 1930; Letterman, 1995; Spencer, 2000). Rickard and Sjoberg (1983) also found that the overall dissolution rate constant is a complex function of temperature.

1.4. Ionic strength:
Rickard and Sjoberg (1983) demonstrated an ionic strength dependence of calcite dissolution rates in their study. In general, solubility of salts increases with increasing ionic strength (Snoeyink and Jenkins, 1980). Since ionic strength is used to calculate the activity coefficients of each carbonate species in water, it also affects the activities of species in equilibrium and dissolution kinetic equations.

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