GLOSSARY AND TERMS

Term

Definition

Action level

The concentration of contaminants set by U.S. EPA that if exceeded requires treatment or other requirements that a water system must follow.

Activity

The effective concentration of a species; usually denoted by { }.

Activity coefficients

The ratio between the active concentration (activity) of a species and the actual concentration of a species (Snoeyink and Jenkins, 1980).

Aeration

Aeration creates a large interfacial surface area between water and air in order to accomplish the transfer of gases between the water and air.

Alkalinity

Alkalinity is the ability to neutralize acid. Alkalinity consists of bases and weak acids. The most common alkalinity forms in natural waters are bicarbonate, HCO3-, carbonate, CO32-, hydroxide, OH-, and ionized silicic acid, H3SiO4-.

AWWA

American Water Works Association.

Ballast

Supplies the proper voltage and current needed for UV lamp operation.

Biodosimetry

A method used to find the reduction equivalent dose (RED). A challenge organism is exposed to UV light in the UV reactor. The inactivation is then measured and compared to the known dose-response curve.

Calcite

Calcite, CaCO3, is a major mineral component of limestone.

Calcium carbonate dissolution potential (CCDP)

CCDP represents the theoretical concentration of calcium carbonate that could dissolve into a water.

Calcium carbonate precipitation potential (CCPP)

CCPP represents the theoretical concentration of calcium carbonate that could precipitate from a water.

Carbonate saturometer

A device used by chemical limnologists and oceanographers to determine the calcium carbonate saturation state based on electrochemical approach (AWWA, 1999).

Challenge Organism

The microorganism selected for use in biodosimetry testing.

CND$

Canadian Dollar.

Collimated Beam Test

A bench-scale test designed to determine the UV dose-response of a microorganism through measurements of exposure time, UV light intensity and the corresponding log-inactivation of the microorganism.

Conductivity

Conductivity is a measure of the ability of a water to conduct electricity. Conductivity is related to ionic strength, i.e. the more ions in solution, the higher the conductivity.

Copper

A metal widely used in household plumbing materials. Copper is an essential nutrient however it may cause stomach and intestinal distress, liver and kidney damage and anemia if ingested at high doses.

Corrosion

Gradual destruction of metals due to electrochemical reactions.

Corrosive water

Corrosive water is a condition of the water’s quality (such as a low pH value, a low alkalinity, a high specific conductivity and high temperature) that will cause the water to dissolve metals from a home’s metallic plumbing at an excessive rate. All water is corrosive toward lead and copper in some degree including water that is termed non-corrosive or water treated to make it less corrosive. The more acidic the water is, the more corrosive the water will become towards lead and copper.

CSIR

CSIR is the premier technology and research organization in South Africa. One of the focus areas of CSIR is a leading center for scientific research for water management in South Africa. The researchers of CSIR have developed several technologies to enable the use of limestone contactor in large water systems such as SSP and Simplified SSP, and for stabilizing groundwater containing iron and manganese such as Spraystab.

Dark Repair

A microbial repair process in which enzymes can regenerate DNA damage by UV light; this process does not require light.

DESCON

A computer program written by Letterman and Kothari (1995) for designing a limestone contactor.

Disequilibrium Index

Disequilibrium Index also known as General Saturation Index is one of the indices used to predict the degree of calcium carbonate saturation in water. For any solid solubility reaction, it is defined as the logarithmic value of the ion activity product divided by the solubility constant (AWWA, 1999).

Dissolution

A reaction where insoluble solid is dissolved in a solution.

Dissolved inorganic carbon (DIC)

Typically, the amount of total carbonates (carbon dioxide gas, CO2 or H2CO3), bicarbonate ion (HCO3-) and carbonate ion (CO32-) in water and measured as milligrams of carbon per liter.

Dolomite

Dolomite is a sedimentary deposit composed mainly of CaMg(CO3)2 as compared to limestone which is mainly CaCO3.

Empty bed contact time (EBCT)

Empty bed contact time is the time it takes for water to flow trough a limestone contactor if no media is present. It is the ratio of the volume of an empty contactor to the flow rate of water flowing through the contactor bed. It is the most important parameter in the design of a limestone contactor for insuring adequate contact time in a limestone bed in order to achieve calcium carbonate saturation.

EPA (same as U.S. EPA)

U.S. Environmental Protection Agency

Equilibrium

A state where no change occurs in a system.

Filtration

A treatment process used to remove suspended solids from water.

Fouling

Deposits on the lamp sleeve, intensity sensor, or sensor window from compounds in the water, may decrease UV light transmittance.

General Saturation Index (same as Disequilibrium Index)

General Saturation Index also known as Disequilibrium Index is one of the indices used to predict the degree of calcium carbonate saturation in water. For any solid solubility reaction, it is defined as the logarithmic value of the ion activity product divided by the solubility constant (AWWA, 1999).

gpm/ft2

Gallon per minute per square foot

Hardness

Hardness in water is caused primarily by the divalent cations calcium, Ca2+, and magnesium, Mg2+. Other divalent cations such as ferrous iron, Fe2+, also contribute to hardness but its concentration is usually much lower than that of calcium and magnesium. Hard waters will cause increased soap consumption for certain kinds of soap as well as the formation of a precipitate or curd on bathroom fixtures. Hardness can also cause scaling or encrustations to form in pipes which gradually reduce the pipe’s diameter and increase the energy losses.

Ionic strength

Ionic strength is a measure of the concentration of ions in solution and is used in calculating activities.

KB,8.2

KB,8.2 is a term used by the engineers and scientists in Germany to express the amount of base needed to titrate water to a pH of 8.2. It is roughly equivalent to acidity and is one of the parameters used in Germany to design a limestone contactor.

KS,4.3

KS,4.3 is a term used by the engineers and scientists in Germany to express the amount of acid needed to titrate water to a pH of 4.3. It is equivalent to total alkalinity and is one of the parameters used in Germany to design a limestone contactor.

Lamp Sleeve

A protective sleeve around the UV lamp typically made of quartz.

Langelier's Index

Langelier’s Index is used to predict the degree of calcium carbonate saturation in water. It is the difference between the actual pH and the hypothetical pH at equilibrium.

Larson's Ratio

Larson's Ratio is a ratio of chloride and sulfate to bicarbonate although some people use the inverse. Some suggest the ration be less than 0.2 to 0.3 if concentrations are in mol/L.

Lead

A metal that was used in household plumbing materials or in water service lines used to bring water from the main to the home. Lead is toxic to human especially to babies, young children and pregnant women. If exposed to lead greater than the maximum contaminant level (MCL), the short term effects may include interference with red blood cells, delays in the normal development in babies and young children and interference with the hearing and learning abilities of children. The long-term effects (if exposed to lead greater than MCL) may include stroke, kidney disease and cancer.

Lead and Copper Rule

A U.S. EPA regulation to control the levels of lead and copper in drinking water.

Long Term 2 Enhanced Surface Water Treatment Rule (LT2ESWTR)

EPA rule to be promulgated to regulate Cryptosporidium in drinking water. Requires 0-2.5 log additional treatment for filtered systems, depending on the source water Cryptosporidium concentration, and 2-3 log treatment for unfiltered systems. Provides requirements for UV reactors for inactivation of Cryptosporidium, Giardia, and viruses.

Low Pressure (LP) Lamp

Lamp that emits UV light at wavelengths of 254 nanometers. Mercury vapor pressure optimal at 0.007 torr.

Low Pressure High Output (LPHO) Lamp

Lamp that emits UV light at wavelengths of 254 nanometers but with a higher UV intensity than low pressure lamps. Mercury vapor pressure 0.76 torr.

Marble Test

A laboratory based test used to determine the relative state of saturation with respect to calcium carbonate.

Maximum Contacminant Level Goal (MCLG)

MCLG is the non-enforceable health goals set at a level at which it will not result in adverse health effects on human and allows an adequate margin of safety.

Maximum Contaminant Level (MCL)

MCL is the maximum allowable concentrations of specific contaminants that is set and enforceable under the Federal Safe Drinking Water Act. If the levels are exceeded, treatment techniques are required.

Medium Pressure (MP) Lamp

Lamp that emits UV light over a range of wavelengths. Mercury vapor pressure 300-30,000 torr.

MLD

106 Liter/Day

Offline Chemical Clean (OCC)

Also known as a flush-and-rinse system; method to clean lamp sleeves where the UV reactor is taken out of service and a cleaning solution is added. After the cleaning solution is removed, the UV reactor goes back online.

Off-specification operation

When the UV reactor does not operate within validated conditions. In most cases, for filtered water the amount of off-specification operation allowed will be up to the states.

Online Mechanical Clean (OMC)

Method to clean lamp sleeves where at set intervals a mechanical wiper cleans the lamp sleeves.

pH

pH is the negative logarithm of the effective hydrogen-ion concentration, pH = -log[H+].

pHc

pHc is the pH of water that is saturated with calcium carbonate.

Photoreactivation

A microbial process requiring light in which enzymes can repair damage caused by UV light.

Precipitation

Formation of insoluble solids in a solution.

PRO/II

The computer software that was initially selected to model the SSP. It modeled all the unit processes involved in the SSP except for the CO2 stripping from the sidestream.

R (or ZAR)

The currency used in South Africa, also known as South African Rand.

Reduction Equivalent Dose (RED)

The dose observed in a full-scale UV reactor determined through biodosimetry testing that correlates to a bench-scale UV dose from collimated beam testing.

Ryznar (Saturation) Index

Ryznar (Saturation) Index is used to predict the degree of calcium carbonate saturation in water. It is the difference between twice the value of hypothetical pH at saturation and the actual pH (AWWA, 1999).

Saturated

A saturated solution has dissolved the maximum amount of a solid, e.g. CaCO3.

Sidestream Stabilization Process (SSP)

A process developed by South African researchers to enable stabilization of water using limestone contactors in large water treatment plants. The process consists of taking a sidestream of unstabilized water, dosing it with carbon dioxide and contacting it with limestone. The remaining CO2 is recovered and reused in the process and the stabilized sidestream blends with the mainstream.

Simplified Sidestream Stabilization Process (Simplified SSP)

Simplified SSP is similar to SSP except the CO2 recovery is not included in the process.

Small system

A small system is a water system serving 3,300 or fewer people (applies only for the Lead and Copper Rule).

Solarization

Effect of UV light on the lamp and sleeve that causes the lamp to become more opaque over time.

Spraystab

A treatment method developed by researchers in South Africa to stabilize groundwater with and without the presence of iron and manganese in the water.

STASOFT

STASOFT is a computer software used to design, model and control water treatment processes that involve carbonate chemistry. It is developed by the Water Research Commission of South Africa and mainly used to aid in the design of limestone contactors in South Africa.

Superficial velocity

The ratio of the water flow rate divided by the cross-sectional area of the contactor bed in which the water flows through.

Supersaturated

A state where a solution contains more solute than a saturated solution at the same temperature. It will thus tend to precipitate the solute.

Supporting media

Supporting media is a term used to describe the media used to support the limestone bed in a limestone contactor or the filtration media in a filter such as gravel, rock and garnet.

Undersaturated

A state where a solution contains less solute than a saturated solution at the same temperature.

US$

U.S. Dollar

UV Absorbance

The reduction in light intensity due to absorption by the transmitting medium, e.g. water, lamp sleeves, or air.

UV Dose

The simplest definition is the amount of ultraviolet light energy per unit area delivered to the water, typically measured in units of mJ/cm2 or J/m2. UV dose delivered to a microorganism is the product of the average UV intensity received by the microorganism from all directions and the exposure time.

UV Dose-Response

Represents inactivation levels of a microorganism as a function of the UV dose.

UV Intensity The power of ultraviolet light per unit area passing through an area perpendicular to the direction of propagation. Describes the magnitude of UV light in a UV reactor (USEPA, 2003).

UV Intensity Sensor

A photosensitive device that measures the UV intensity at a specific location in a UV reactor.

UV Light

Light that is emitted with wavelengths from 200 to 400 nanometers.

UV Reactor

The chamber where water is treated with UV light. Lamps, lamp sleeves, sensors and wiper cleaning system are also considered part of the reactor.

UV Reactor Validation

A process for verifying the reactor performance over a range of operating conditions.

UV Transmittance (UVT)

The fraction of light intensity entering the water compared to the amount of light leaving. UVT = 10-UVA.

WATCHEM

WATCHEM is one of the computer programs included in the STASOFT 4 package used to model the Simplified SSP by the South African researchers.

ZAR

The currency used in South Africa, also known as South African Rand.