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Research Projects
Geochemical Weathering
Surfactant-Induced Permeability Changes
Beneficial Use of Contaminated Sediment
Risk Assessment Model for Secondary Materials
Use
Coating Diatomaceous Earth with Oxides for NOM
Removal
In-Situ Reactive Wall Formation with
Colloidal Materials
Geochemical Weathering
Reactions in Granular Byproduct Materials
Funding: Recycled Materials Resource
Center / Federal Highway Administration
Description: This project focuses on
the mechanisms by which leaching behavior is altered during chemical
weathering of recycled materials.
Leaching of metals is one of the primary concerns related to the
beneficial use of byproduct materials, but is a phenomenon that
will change significantly over time as glassy, amorphous materials
from high-temperature processes weather to form more stable secondary
minerals. This project is being undertaken to understand how leaching
is effected, what the kinetics of the pertinent reactions are, and
how estimates of long-term contaminant release are impacted. The
materials that are being investigated include coal fly ash, coal
bottom ash, aluminum dross, and municipal solid waste incinerator
bottom and fly ash.
Graduate Student: Bob Carter
Investigation of Mechanisms
of Surfactant-Induced Hydraulic Conductivity Changes in Soil Flushing
Operations
Funding: National Science Foundation
Description: A major concern with the
use of surfactant flushing to mobilize non-aqueous phase liquids
in aquifers is specific mineral-surfactant interactions which may
effect significant permeability changes in the soil formation. Soils
are being investigated for loss of permeability upon flushing with
solution containing a number of nonionic and anionic surfactants.
Surfactant / clay interactions are being further investigated as
the cause of the permeability reductions, both from transport/rearrangement
and swelling.
Graduate Student: Chris Berg
Related References:
Gardner, K.H., M. S. Arias, "Clay Swelling and Formation
Permeability Reductions Induced by a Nonionic Surfactant,"
Environmental Science and Technology 34(1), 160-166 (2000).
Development of Reuse Alternatives
for the Management of Dredged, Contaminated Sediments,
Funding: Cooperative Institute
for Coastal and Estuarine Environmental Technology
Description: This research is investigating
the potential to beneficially use contaminated sediment dredged
for navigational purposes as an alternative mineral source for the
manufacture of cement. We are working with Blue Circle Cement, in
Ravena, NY, the NYS DEC, US EPA, and US ACOE on this research, and
are planning to expand this research to a full-scale demonstration
project in 2001-2002.
Graduate Student: Mindy Weimer
Related References:
Gardner, K.H., B. Magee, J. Dalton, L. Roberts "Beneficial
Use of Dredged Sediments as a Partial Feedstock Material in Portland
Cement Manufacture," Conference on Options for Dredged Material
Disposal Management, Massachusetts Institute of Technology,
Cambridge, MA. December, 2000.
Development of Application-Specific
Source Term /Fate/Transport Models and Approaches for Recycled Materials
Use in the Highway Environment
Funding: Recycled Materials Resource
Center / Federal Highway Administration
Description:This project is being conducted
to answer the following questions:
How should States decide whether a secondary material is safe for
use in different types of applications?
What are the risks associated with using a byproduct that may have
some elevated levels of contaminants, and how can this risk be quantified?
Should the TCLP be used to provide a best estimate of concentrations
of contaminants in leachates, or are there approaches that will
more accurately assess this?
Graduate Student: Defne Apul
Coating of Diatomaceous Earth
Filter Media with Hydrous Oxides for the Removal of Disinfection Byproduct
Precursors and Arsenic.
Funding: Water Treatment Technology
Assistance Center / Environmental Protection Agency
Description: Many utilities are being
faced with having to remove NOM and arsenic to increasingly stringent
levels. This research will investigate the efficacy of coating DE
with various types of sorbents to remove As and NOM.
Graduate Student: Mark Arenberg
In-Situ Reactive Wall Formation
with Colloidal Materials.
Description: These projects are focused
on putting reactive barrier walls in place by colloid deposition.
The advantages are that much less material is required and deep
contamination or inaccessible areas are not a problem as they are
with trench and backfill approaches.
Related References:
Bower,K.C., K.H. Gardner, C.M. Miller, and L. Kong, "In-Situ Colloidal
MnO2 Deposition and Ozonation of 2,4-Dinitrotoluene," Environmental
Engineering and Science (In Press).
Gardner, K.H., C.M. Miller, L. Kong, "Placement of a Colloidal-Catalyst
In Situ Reactive Treatment Wall," Second International Conference
on Remediation of Chlorinated and Recalcitrant Compounds, Monterey,
California May 22-25, 2000.
Miller, C. M., K. Bower, S. Duirk, and K. H. Gardner, "Metal
Oxide-Coated Sand-Catalyzed Ozonation of 2,4-Dinitrotoluene,"
Second International Conference on Remediation of Chlorinated and
Recalcitrant Compounds, Monterey, California, May 22-25, 2000

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